To provide a method for producing an optically active 1,2-diamine compound in high yield and high stereoselectivity using a niobium catalyst having an optically active polyhydric alcohol as a ligand and to provide the optically active niobium catalyst. ;SOLUTION: An optically active aziridine compound is reacted with an aromatic amine compound in a reaction system obtained by mixing a niobium compound with an optically active tetrol represented by formula (I) or an antipode thereof in an organic solvent. Thereby, the optically active 1,2-diamine compound is produced.

METHOD FOR PRODUCING OPTICALLY ACTIVE 1,2-DIAMINE COMPOUND AND OPTICALLY ACTIVE NIOBIUM CATALYST

LUCARINI, SIMONE
2007-01-01

Abstract

To provide a method for producing an optically active 1,2-diamine compound in high yield and high stereoselectivity using a niobium catalyst having an optically active polyhydric alcohol as a ligand and to provide the optically active niobium catalyst. ;SOLUTION: An optically active aziridine compound is reacted with an aromatic amine compound in a reaction system obtained by mixing a niobium compound with an optically active tetrol represented by formula (I) or an antipode thereof in an organic solvent. Thereby, the optically active 1,2-diamine compound is produced.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11576/2506452
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