A dinuclear Ni(II)-Zn(II) complex of 2-bis-(aminoethyl)-aminomethylphenol (L) was prepared by mixing the homo-dinuclear complexes of Ni(II) and Zn(II). The mixed hetero-dinuclear complex was characterized by X-ray analysis. Crystal data for the compound [NiZn(H -1L) 2(H 2O) 2][ClO 4] 2 revealed that it is monoclinic; space group P2 1/n with a=20.137(2) Å, b=9.480(1) Å, c=15.934(1) Å, β=100.45(1)°, V =2991.3(5) Å 3, Z=4, R=0.094.
Crystal Structure and Chemical Properties of Ni(II)-Zn(II) Hetero-Dinuclear Complex
MICHELONI, MAURO SERGIO;AMBROSI, GIANLUCA;FORMICA, MAURO;FUSI, VIERI;GIORGI, LUCA;
2002
Abstract
A dinuclear Ni(II)-Zn(II) complex of 2-bis-(aminoethyl)-aminomethylphenol (L) was prepared by mixing the homo-dinuclear complexes of Ni(II) and Zn(II). The mixed hetero-dinuclear complex was characterized by X-ray analysis. Crystal data for the compound [NiZn(H -1L) 2(H 2O) 2][ClO 4] 2 revealed that it is monoclinic; space group P2 1/n with a=20.137(2) Å, b=9.480(1) Å, c=15.934(1) Å, β=100.45(1)°, V =2991.3(5) Å 3, Z=4, R=0.094.File in questo prodotto:
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