Increasing data (INAA) on Ecuadorian obsidian artifacts: preliminary provenance and a clue for pre-Columbian eastward trade

In this work we carried out INAA major (Na, K, Ca and Fe %) and trace (ppm) elements (plus Mn by FAAS analysis) of 15 obsidian samples (waste flakes) coming from an unknown archaeological site (14C-AMS age of 1425 AD) located on the south-eastern flank of the back-arc Sumaco volcano (to the east of the Cordillera Real) and from two already known pre-Columbian archaeological localities: La Florida (Quito) and Milan (Cayambe). Literature compositional data of the Ecuadorian obsidian outcrops provide some constraints on the provenance of the analyzed waste flakes, even though different methods of analyses make comparisons a difficult task. Concerning the obsidian artifacts of La Florida and Milan, they come from the well known Sierra de Guamanı` obsidian sources (Cordillera Real). By contrast, the obsidian fragments of the Sumaco settlement show some compositional characters compatible with obsidian erratic pebbles recently discovered in some river banks of the Amazonian foothills draining the easternmost flanks of the Antisana volcano in the Cordillera Real as well. In this way, the obsidian artifacts found at the Sumaco site reinforce the opinion that Ecuadorian source inventory is not yet exhaustive. Although the Antisana volcano seems to be the best candidate to find out additional primary outcrops of obsidian sources, it cannot be also excluded that sub-Andean and Amazonian people directly took advantage from obsidian secondary sources (e.g. river banks), rather than procurements from primary outcrops in the Cordillera Real. The new archaeological findings at the Sumaco volcano are really of paramount importance in tracing the ancient routes of a possible obsidian eastward trade toward the Amazonian region.