Herein we report a domino protocol able to reach regioselectively thiazolylidene systems by combining the reactive peculiarities both of -amidothioamides (ATAs) and 1,2-diaza-1,3-dienes (DDs). Depending on the reaction conditions and/or the nature of the residue at C4 of the heterodiene system, ATAs can act as hetero mononucleophiles or hetero dinucleophiles in the diversified thiazolylidene ring assembly.
Divergent Approach to Thiazolylidene derivatives: a Perspective in the Synthesis of Heterocyclic Skeleton from beta-Amidothioamides Reactivity
SANTEUSANIO, STEFANIA;MAJER, ROBERTA;PERRULLI, FRANCESCA ROMANA;DE CRESCENTINI, LUCIA;FAVI, GIANFRANCO;MANTELLINI, FABIO
2017
Abstract
Herein we report a domino protocol able to reach regioselectively thiazolylidene systems by combining the reactive peculiarities both of -amidothioamides (ATAs) and 1,2-diaza-1,3-dienes (DDs). Depending on the reaction conditions and/or the nature of the residue at C4 of the heterodiene system, ATAs can act as hetero mononucleophiles or hetero dinucleophiles in the diversified thiazolylidene ring assembly.File in questo prodotto:
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